Università degli Studi di Cagliari
A Facile Synthesis of a Push-Pull Mixed-Ligand Pd-Dithiolene Complex Containing the Et2timdt Ligand (Et2timdt = Monoreduced Diethylimidazolidine-2,4,5-trithione)
ARAGONI, MARIA CARLA;ARCA, MASSIMILIANO;ISAIA, FRANCESCO;LIPPOLIS, VITO;
2003-01-01
Abstract
The reaction of the dithiolene [Pd(Et2timdt)2] (Et2timdt = formally monoreduced diethylimidazolidine-2,4,5-trithione) with Br2 or IBr yields the complex [Pd(Et2timdt)Br2], a good starting material for the synthesis of novel push-pull mixed-ligand Pd-dithiolenes. The synthesis and characterisation of the unsymmetrical dithiolene [Pd(Et2timdt)(mnt)] (mnt = maleonitriledithiolato dianion) is also reported.
File in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
| I02641KAP1.pdf Solo gestori archivio
Tipologia: versione editoriale
Dimensione 110.3 kB
Formato Adobe PDF
|
110.3 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.