An unusual cis-phosphonodithioato Pd(II) complex in an extensive hydrogen bonding 3D network

ARAGONI, MARIA CARLA;ARCA, MASSIMILIANO;DEMARTIN F;DEVILLANOVA FA;ISAIA, FRANCESCO;LIPPOLIS, VITO;VERANI G.

2005-01-01

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Abstract

The P–N bond hydrolysis of the 4-methoxyphenyl-ammoniumethylamido-phosphonodithioato ligand on complexation to PdII leads to the first example of a Pd-phosphonodithioato complex in a cis configuration, stabilised in the solid state by an extended network of hydrogen bondings involving the released ethylenediamine and a water molecule.