1,4-Bis(2'-pyridylethynyl)benzene as a ligand in heteronuclear gold–thallium complexes. Influence of the ancillary ligands on their optical properties

ARCA, MASSIMILIANO;Donamaría R;Gimeno M. C;LIPPOLIS, VITO;López de Luzuriaga J. M;Manso E;Monge M;Olmos M. E.

2015-01-01

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Abstract

The reaction of 1,4-bis(2’-pyridylethynyl)benzene (L) with [{Au(C6X5)2}Tl]n affords new heterometallic AuI/ TlI complexes with different stoichiometries, structural arrangements and optical properties depending on the halogens present in the aryl group. The chlorinated derivative [{Au(C6Cl5)2}Tl(L)]n (1) displays polymeric chains built thanks to unsupported Au⋯Tl interactions and bridging bidentate ligands between adjacent chains, while in the fluorinated species [{Au(C6F5)2}2Tl2(L)2]n (2), also containing N-donor bridging ligands and Au⋯Tl contacts, polymerization occurs via Tl⋯Caryl non-bonding interactions between neighbouring molecules. The optical properties of 1 and 2 have been studied experimentally and theoretically, conclud- ing that the luminescence of 1 in the solid state has its origin in the Au⋯Tl interactions, and that the Tl⋯Caryl interactions in 2 favour a non-radiative deactivation pathway that avoids luminescence. The strength of the non-bonding interactions present in 1 has also been theoretically studied at the HF and MP2 levels, revealing the metallophilic contact as the strongest one.