Maria Cristina Secci
Selecting molecular or surface centers in carbon dots-silica hybrids to tune the optical emission: A photo-physics study down to the atomistic level
Olla, Chiara
;Ricci, Pier Carlo;Chiriu, Daniele;Fantauzzi, Marzia;Casula, Maria Francesca;Mocci, Francesca;Cappai, Antonio;Porcu, Stefania;Stagi, Luigi;Carbonaro, Carlo Maria
2023-01-01
Abstract
In this work, we unveil the fluorescence features of citric acid and urea-based Carbon Dots (CDs) through a photo-physical characterization of nanoparticles synthesized, under solvent-free and open-air condi-tions, within silica-ordered mesoporous silica, as a potential host for solid-state emitting hybrids. Compared to CDs synthesized without silica matrices and dispersed in water, silica-CD hybrids display a broader emission in the green range whose contribution can be increased by UV and blue laser irradi-ation. The analysis of hybrids synthesized within different silica (MCM-48 and SBA-15) calls for an active role of the matrix in directing the synthesis toward the formation of CDs with a larger content of graphitic N and imidic groups at the expense of N-pyridinic molecules. As a result, CDs tuned in size and with a larger green emission are obtained in the hybrids and are retained once extracted from the silica matrix and dispersed in water. The kinetics of the photo-physics under UV and blue irradiation of hybrid samples show a photo-assisted formation process leading to a further increase of the relative contribution of the green emission, not observed in the water-dispersed reference samples, suggesting that the porous matrix is involved also in the photo-activated process. Finally, we carried out DFT and TD-DFT calcula-tions on the interaction of silica with selected models of CD emitting centers, like surface functional groups (OH and COOH), dopants (graphitic N), and citric acid-based molecules. The combined experimen-tal and theoretical results clearly indicate the presence of molecular species and surface centers both emitting in the blue and green spectral range, whose relative contribution is tuned by the interaction with the surrounding media.File | Size | Format | |
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PaperSCDN_JCI_pre_print_version.pdf open access
Type: versione pre-print
Size 3.42 MB
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PaperSCDN_JCI_accepted_version.pdf Solo gestori archivio
Type: versione editoriale
Size 5.21 MB
Format Adobe PDF
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5.21 MB | Adobe PDF | & nbsp; View / Open Request a copy |
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