University of Cagliari
Catalytic enantioselective synthesis of α-arylaminocyclobutanones
CABONI, PIERLUIGI;FRONGIA, ANGELO;SECCI, FRANCESCO
2014-01-01
Abstract
A catalytic enantioselective synthesis of α-arylaminocyclobutanones from racemic α-hydroxycyclobutanone and a selection of N-alkylanilines has been established, via a tandem condensation/keto-enol tautomerization process reminiscent of the Amadori and Heyns rearrangements.
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