A Facile Synthesis of a Push-Pull Mixed-Ligand Pd-Dithiolene Complex Containing the Et2timdt Ligand (Et2timdt = Monoreduced Diethylimidazolidine-2,4,5-trithione)

ARAGONI, MARIA CARLA;ARCA, MASSIMILIANO;ISAIA, FRANCESCO;LIPPOLIS, VITO;
2003-01-01

Abstract

The reaction of the dithiolene [Pd(Et2timdt)2] (Et2timdt = formally monoreduced diethylimidazolidine-2,4,5-trithione) with Br2 or IBr yields the complex [Pd(Et2timdt)Br2], a good starting material for the synthesis of novel push-pull mixed-ligand Pd-dithiolenes. The synthesis and characterisation of the unsymmetrical dithiolene [Pd(Et2timdt)(mnt)] (mnt = maleonitriledithiolato dianion) is also reported.
2003
Inglese
2003
7
1291
1295
5
WOS:000182357800002
2-s2.0-0037395049
Esperti anonimi
scientifica
sì
Aragoni, MARIA CARLA; Arca, Massimiliano; C., Denotti; F. A., Devillanova; E., Grigiotti; Isaia, Francesco; F., Laschi; Lippolis, Vito; L., Pala; A. M. Z., Slawin; P., Zanello; J. D., Woollins
1.1 Articolo in rivista
info:eu-repo/semantics/article
1 Contributo su Rivista::1.1 Articolo in rivista
262
12
reserved
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