Reactivity of phosphonodithioato-dppt NiII mixed ligand complexes with halogens: first example of a metal-coordinating tribromide anion

ARAGONI, MARIA CARLA;ARCA, MASSIMILIANO;Coles S. L;Devillanova F. A;Hursthouse M. B;ISAIA, FRANCESCO;LIPPOLIS, VITO

2012-01-01

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Abstract

The first example of a metal complex containing a tribromide anion is presented and characterised by X-ray diffraction. Hybrid DFT calculations were used to investigate the nature of the bond in coordinating trihalides and the differences with the corresponding mono-halide complexes.