Extending the Hammett correlation to mechanochemical reactions
Carta M.Member of the Collaboration Group
;Delogu F.Conceptualization
;
2023-01-01
Abstract
Using Raman in situ monitoring and mechanochemistry-specific kinetic analysis, we find a correlation between the reaction probability and the Hammett constants in a model mechanochemical reaction of imine formation, indicating that the body of knowledge developed in physical-organic chemistry could be transferable to ball milling reactions in the solid state.Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.