A Visible-Light Driven Esterification of Aldehydes Catalyzed by VOSO4
Gaspa S.First
Investigation
;d'Atri D.Member of the Collaboration Group
;Porcheddu A.;Carraro M.Member of the Collaboration Group
;
2023-01-01
Abstract
An esterification of the C-H bond of aldehydes promoted by oxidovanadium(IV) sulfate, (VOSO4)-O-IV, is reported. The process is mediated by visible-light, is carried out at room temperature, in absence of additives and using H2O2 as a benign oxidant. VOSO4 is a commercially available, earth-abundant metal (EAM(s)) salt, that does not require to be prepared. This report opens intriguing perspectives for the extended application of vanadium salts toward halogenation processes as well as for C-H activations and gives a contribution in the field of earth-abundant metals based-catalysis.File | Size | Format | |
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Adv Synth Catal - 2023 - Gaspa-Copia.pdf open access
Type: versione editoriale
Size 5.06 MB
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5.06 MB | Adobe PDF | View/Open |
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