Combined Experimental/Theoretical Study on the Luminescent Properties of Homoleptic/Heteroleptic Erbium(III) Anilate-Based 2D Coordination Polymers

Ashoka Sahadevan S.

First

;Manna F.;Abherve A.;Oggianu M.;Monni N.;Mameli V.;Marongiu D.;Quochi F.;Gendron F.;Le Guennic B.;Avarvari N.

;Mercuri M. L.

2021-01-01

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Abstract

The synthesis, structural and photophysical characterization, and theoretical studies on homo/heteroleptic neutral 2D-layered coordination polymers (CPs), obtained by combining the ErIII ion with chlorocyananilate (ClCNAn) and/or tetrafluoroterephthalate (F4BDC) linkers, are herein reported. The structure of the heteroleptic ErIII-based CP, formulated as [Er2(ClCNAn)2(F4BDC)(DMSO)6]n (1) is also reported. 1 crystallizes in the triclinic P1¯ space group, and the structure consists of neutral 2D layers formed by ErIII ions linked through the two linkers oriented in such a way that the neighboring 2D layers are eclipsed along the a axis, leading to parallelogram-like cavities. Photophysical measurements highlight the prominent role of chlorocyananilate linkers as optical antennas toward lanthanide ions, while wave-function-theory analysis supports the experimental findings, providing evidence for the effect of ligand substitution on the luminescence properties of homo/heteroleptic 2D CPs.