Isocyanide insertion into Au-H bonds: First gold iminoformyl complexes
Pintus A.;
2018-01-01
Abstract
Isocyanides insert into gold(iii)-hydrogen bonds to give the first examples of gold iminoformyl complexes. The reaction is initiated by catalytic amounts of radicals; DFT calculations indicate that this is an equilibrium reaction driven forward by isocyanide in sufficient excess to trap the Au(ii) intermediate.File | Size | Format | |
---|---|---|---|
Iminoformyl ChemCom template.pdf Solo gestori archivio
Type: versione pre-print
Size 464.05 kB
Format Adobe PDF
|
464.05 kB | Adobe PDF | & nbsp; View / Open Request a copy |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.