Acid-catalyzed synthesis of functionalized arylthio cyclopropane carbaldehydes and ketones

Porcu, Stefania
First
;Luridiana, Alberto;Frongia, Angelo;Sarais, Giorgia;Secci, Francesco
Last
2018-01-01

Abstract

A general strategy for the synthesis of arylthio cyclopropyl carbaldehydes and ketones via a Brønsted acid catalyzed arylthiol addition/ring contraction reaction sequence has been exploited. The procedure led to a wide panel of cyclopropyl carbaldehydes in generally high yields and with broad substrate scope. Mechanistic aspects and synthetic applications of this procedure were investigated.
2018
Catalysis; Electronic, Optical and Magnetic Materials; Ceramics and Composites; Chemistry (all); Surfaces, Coatings and Films; 2506; Materials Chemistry2506 Metals and Alloys
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