University of Cagliari
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Structural diversity in the products formed by the reactions of 2-arylselanyl pyridine derivatives and dihalogens
M. ArcaMember of the Collaboration Group
;M. Carla Aragoni
Member of the Collaboration Group
;F. DemartinMember of the Collaboration Group
;F. IsaiaMember of the Collaboration Group
;V. Lippolis
Member of the Collaboration Group
;A. PintusMember of the Collaboration Group
;
2018-01-01
Abstract
The reactivity of the 2-arylselanyl pyridine derivatives L1–L4 towards dihalogens X2 (X = I, Br) and interhalogens IX (X = Cl, Br) was studied in CHCl3 or CH3CN. The solid products obtained were structurally characterized and their nature points out the preference for CT spoke adducts and for seesaw insertion adducts to be formed at the N-donor and Se-donor site, respectively. DFT calculations were performed to provide a rationale for the structural diversity observed in the products obtained
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| File | Size | Format | |
|---|---|---|---|
| 306 NJC 2018.pdf Solo gestori archivio
Description: pdf
Type: versione editoriale
Size 2.65 MB
Format Adobe PDF
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2.65 MB | Adobe PDF | & nbsp; View / Open Request a copy |
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