Optically Multiresponsive Heteroleptic Platinum Dithiolene Complex with Proton-Switchable Properties
ATTAR, SALAHUDDIN SAYEDSHABBIR;ESPA, DAVIDE;ARTIZZU, FLAVIA;PILIA, LUCA;SERPE, ANGELA;DEPLANO, PAOLA
2017-01-01
Abstract
Both linear- and nonlinear-optical properties of Bu4N[Pt(L1)(L2)] (1; L1 = [4',5':5,6][1,4]dithiino[2,3-b]quinoxaline-1',3'dithiolato; L2 = (R)-α-MBAdto dithiooxamidate, where (R)-α-MBA = (R)-(+)-α-methylbenzyl) upon HCl addition at room temperature change dramatically: the color turns from deep blue to green; the luminescence switches from deep red to green; the nonlinear-optical response (first hyperpolarizability) increases by a factor of 12. Thus, 1 behaves as a unique multiresponsive optical switch whose properties can be followed by the naked eye.File | Size | Format | |
---|---|---|---|
Inorg Chem 2017.pdf Open Access from 26/05/2018
Description: Articolo principale
Type: versione post-print
Size 1.14 MB
Format Adobe PDF
|
1.14 MB | Adobe PDF | View/Open |
Pilia et al_Inorganic chemistry_2017.pdf Solo gestori archivio
Description: articolo
Type: versione editoriale
Size 8.64 MB
Format Adobe PDF
|
8.64 MB | Adobe PDF | & nbsp; View / Open Request a copy |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.