Redox Switchable Chromophores based on Metal (Ni, Pd, Pt) Mixed-Ligand Dithiolene Complexes Showing Molecular Second-order NLO Activity

ESPA, DAVIDE;PILIA, LUCA;MERCURI, MARIA LAURA;SERPE, ANGELA;DEPLANO, PAOLA
2011-01-01

Abstract

The synthesis and full characterization of the redox-active nickel triad mixed-ligand dithiolene complexes based on Bz2pipdt = 1,4-dibenzylpiperazine-3,2-dithione and dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate ligands are reported. These complexes show a reversibly bleacheable solvatochromic peak and a remarkably high negative molecular first hyperpolarizability, whose values depend on the metal being highest for the platinum(II) compound
2011
INORGANIC CHEMISTRY
50
6
2058
2060
3
WOS:000288182700008
2-s2.0-79954443337
http://pubs.acs.org/doi/abs/10.1021/ic102343g?prevSearch=%255Bauthor%253A%2Bespa%255D%2BNOT%2B%255Batype%253A%2Bad%255D%2BNOT%2B%255Batype%253A%2Bacs-toc%255D&searchHistoryKey=
Esperti anonimi
Communication
Espa, Davide; Pilia, Luca; L., Marchio; Mercuri, MARIA LAURA; Serpe, Angela; A., Barsella; A., Fort; S. J., Dalgleish; N., Robertson; Deplano, Paola ...espandi
1.1 Articolo in rivista
info:eu-repo/semantics/article
1 Contributo su Rivista::1.1 Articolo in rivista
262
10
none
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